There's nothing wrong with your query--I just don't think the W3Schools online database tool supports the EXCEPT clause. You would need to download a database that supports the EXCEPT clause if you wanted to practice it (SQL Server, Oracle DB, PostgreSQL).
Try this equivalent (and more performant) query
select orderid
from orders
where customerid >= 100
The EXCEPT clause runs but there are not customerid greater or equal than 100.